Metadata about: Abstract Ozone (O3) pollution has aroused increasing attention in China in past years, especially in the Yangtze River Delta (YRD), eastern China. Ozone and its precursors generally feature different diurnal patterns, which is closely related to atmospheric physical and chemical processes. This work aims to shed more light on the causes of ozone pollution from the perspective of the diurnal patterns. Hundreds of ozone pollution days (with maximum hourly O3 concentration over 100 ppb) during 2013–2017 were identified and then clustered into 4 typical types according to the diurnal variation patterns. We found that ozone pollution in Shanghai was particularly severe when anthropogenic pollutant mixed with biogenic volatile organic compounds (BVOCs) under the prevailing southwesterly wind in summer. The reason could be attributed to the spatial disparities of ozone sensitivity regime in YRD: VOC-limited regime around in the urban area and NOx-limited regime in the rural forest regions in the southern and southwest. The transition of sensitivity regimes along south/southwest wind tended to promote the photochemical production of ozone, making daily O3 pollution time exceeding 6 h of the day. In addition, ozone peak concentration in Shanghai was highly dependent on the evolution of sea-land breezes (SLBs). Earlier sea breeze associated with approaching typhoon in the West Pacific caused less cloud (−25%) and more solar radiation (11%) in YRD, which subsequently led to a rapid increase of O3 concentration in the morning and a deteriorated ozone pollution during noon and the afternoon. This study highlights the importance of observation-based processes understanding in air quality studies.

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