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About:
Chemical synthesis and optical, structural, and surface characterization of InP - In(2)O(3) quantum dots
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covidontheweb.inria.fr
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Academic Article
research paper
schema:ScholarlyArticle
isDefinedBy
Covid-on-the-Web dataset
has title
Chemical synthesis and optical, structural, and surface characterization of InP - In(2)O(3) quantum dots
Creator
Durán-Ledezma, Angel
Pérez-González, M
Arias-Cerón, J
Cruz-Orea, A
Durán-Ledezma, A
Granada-Ramirez, D
Gómez Herrera, M
Herrera-Pérez, J
Luna-Arias, J
Mendoza-Alvarez, J
Rodríguez-Fragoso, P
Tomás, S
Vázquez-Hernández, F
Source
Elsevier; Medline; PMC
abstract
InP-In(2)O(3) colloidal quantum dots (QDs) synthesized by a single-step chemical method without injection of hot precursors (one-pot) were investigated. Specifically, the effect of the tris(trimethylsilyl)phosphine, P(TMS)(3), precursor concentration on the QDs properties was studied to effectively control the size and shape of the samples with a minimum size dispersion. The effect of the P(TMS)(3) precursor concentration on the optical, structural, chemical surface, and electronic properties of InP-In(2)O(3) QDs is discussed. The absorption spectra of InP-In(2)O(3) colloids, obtained by both UV-Vis spectrophotometry and photoacoustic spectroscopy, showed a red-shift in the high-energy regime as the concentration of the P(TMS)(3) increased. In addition, these results were used to determine the band-gap energy of the InP-In(2)O(3) nanoparticles, which changed between 2.0 and 2.9 eV. This was confirmed by Photoluminescence spectroscopy, where a broad-band emission displayed from 2.0 to 2.9 eV is associated with the excitonic transition of the InP and In(2)O(3) QDs. In(2)O(3) and InP QDs with diameters ranging approximately from 8 to 10 nm and 6 to 9 nm were respectively found by HR-TEM. The formation of the InP and In(2)O(3) phases was confirmed by X-ray Photoelectron Spectroscopy.
has issue date
2020-07-22
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bibo:doi
10.1016/j.apsusc.2020.147294
bibo:pmid
32834267
has license
no-cc
sha1sum (hex)
1a022b9579fbbdf76f47b96e5f43816f3d2dad21
schema:url
https://doi.org/10.1016/j.apsusc.2020.147294
resource representing a document's title
Chemical synthesis and optical, structural, and surface characterization of InP - In(2)O(3) quantum dots
has PubMed Central identifier
PMC7375344
has PubMed identifier
32834267
schema:publication
Appl Surf Sci
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covid:1a022b9579fbbdf76f47b96e5f43816f3d2dad21#body_text
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schema:about
of
named entity 'dots'
named entity 'surface'
named entity 'InP'
named entity 'quantum dots'
named entity 'UV-Vis-NIR'
named entity 'XRD'
named entity 'solvothermal'
named entity 'SARS-CoV-2'
named entity 'InO'
named entity '0.9'
named entity '1, 2'
named entity 'X-ray'
named entity 'luminescent'
named entity '3/4'
named entity 'spectra'
named entity 'peak-to-peak'
named entity 'oxygen'
named entity 'oxygen'
named entity 'oxygen'
named entity 'valence electron'
named entity 'Colloidal'
named entity 'photoelectron'
named entity 'hydrocarbon'
named entity 'core-level'
named entity 'colloidal'
named entity 'Rigaku'
named entity 'CBI'
named entity 'nanoparticles'
named entity 'anions and cations'
named entity 'chemical analysis'
named entity 'molecular compounds'
named entity 'InP'
named entity 'spectral region'
named entity 'amplitude'
named entity 'orbital angular momentum'
named entity 'NIR'
named entity 'colloidal'
named entity 'zinc blende structure'
named entity 'quantum dots'
named entity 'valence electrons'
named entity 'HR-TEM'
named entity 'valence band'
named entity 'InP'
named entity 'acetone'
named entity 'InP'
named entity 'InP'
named entity 'valence band'
named entity 'spectrophotometry'
named entity 'InP'
named entity 'X-ray Photoelectron Spectroscopy'
named entity 'photon energy'
named entity 'luminescence'
named entity 'organic solvents'
named entity 'high-energy'
named entity 'high-energy'
named entity 'diffractometer'
named entity 's-subshells'
named entity 'colloidal'
named entity 'luminescent'
named entity 'X-Ray Photoelectron Spectroscopy'
named entity 'core-level'
named entity 'SAED'
named entity 'Carbon'
named entity 'silicon'
named entity 'spectrophotometry'
named entity 'myristic acid'
named entity 'InP'
named entity 'high resolution'
named entity 'quantum dots'
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